HallHeroult process
HallHeroult process The HallHeroult process is the major industrial process for the production of aluminum.. In the HallHeroult process alumina, Al 2 O 3 is dissolved in a carbonlined bath of molten cryolite, Na 3 AlF fluoride, AlF 3 is also present to reduce the melting point of the cryolite. The mixture is electrolyzed, and liquid aluminum is produced at the cathode.